While answering PHP rename() doesn't throws exception on error I was wondering if there are any native PHP functions which throw a built-in Exception, beside the SPL stuff?
Not really. If you read the note on that page you linked:
Note:
Internal PHP functions mainly use Error reporting, only modern Object oriented extensions use exceptions. However, errors can be simply translated to exceptions with ErrorException.
PHP 5 has an exception model similar to that of other programming languages.
来源:https://stackoverflow.com/questions/10607539/is-there-any-native-php-function-which-throws-an-built-in-exception