stringr

What I am trying to accomplish is splitting a column into multiple columns. I would prefer the first column to contain "F", second column "US", third "CA6" or "DL", and the fourth to be "Z13" or "U13" etc etc. My entire df follows the same pattern of X.XX.XXXX.XXX or X.XX.XXX.XXX or X.XX.XX.XXX and I know the third column is where my problem lies because of the different lengths. I have only used substr in the past and I could use that here with some if statements but would like to learn how to use stringr package and POSIX to do this (unless there is a better option). Thank you in advance.