I\'m trying to build a simple calculator in Angular in which I can override the total if I want. I have this part working but when I then go back to enter in a number in fields
I'm guessing that when you enter a value into the totals field that value expression somehow gets overwritten.
However, you can take an alternative approach: Create a field for the total value and when either one or two changes update that field.
<li>Total <input type="text" ng-model="total">{{total}}</li>
And change the javascript:
function TodoCtrl($scope) {
    $scope.$watch('one * two', function (value) {
        $scope.total = value;
    });
}
Example fiddle here.
You just need to correct the format of your html
<form>
    <li>Number 1: <input type="text" ng-model="one"/> </li>
    <li>Number 2: <input type="text" ng-model="two"/> </li>
        <li>Total <input type="text" value="{{total()}}"/>  </li>      
    {{total()}}
</form>
http://jsfiddle.net/YUza7/105/
I wrote a directive you can use to bind an ng-model to any expression you want. Whenever the expression changes the model is set to the new value.
 module.directive('boundModel', function() {
      return {
        require: 'ngModel',
        link: function(scope, elem, attrs, ngModel) {
          var boundModel$watcher = scope.$watch(attrs.boundModel, function(newValue, oldValue) {
            if(newValue != oldValue) {
              ngModel.$setViewValue(newValue);
              ngModel.$render();
            }
          });
          // When $destroy is fired stop watching the change.
          // If you don't, and you come back on your state
          // you'll have two watcher watching the same properties
          scope.$on('$destroy', function() {
              boundModel$watcher();
          });
        }
    });
You can use it in your templates like this:
 <li>Total<input type="text" ng-model="total" bound-model="one * two"></li>      
Create a directive and put a watch on it.
app.directive("myApp", function(){
link:function(scope){
    function:getTotal(){
    ..do your maths here
    }
    scope.$watch('one', getTotals());
    scope.$watch('two', getTotals());
   }
})
You can add ng-change directive to input fields. Have a look at the docs example.