I have an \'intranet\' site that I have built, which has a login system of its own (users register as new users, and use the username/password thereon to login to the site). How
Here is what I use:
<?php
error_reporting(E_ALL);
ini_set('display_errors', 'On');
define('DOMAIN_FQDN', 'mycompany.intra');
define('LDAP_SERVER', '192.168.0.1');
if (isset($_POST['submit']))
{
    $user = strip_tags($_POST['username']) .'@'. DOMAIN_FQDN;
    $pass = stripslashes($_POST['password']);
    $conn = ldap_connect("ldap://". LDAP_SERVER ."/");
    if (!$conn)
        $err = 'Could not connect to LDAP server';
    else
    {
        define('LDAP_OPT_DIAGNOSTIC_MESSAGE', 0x0032);
        ldap_set_option($conn, LDAP_OPT_PROTOCOL_VERSION, 3);
        ldap_set_option($conn, LDAP_OPT_REFERRALS, 0);
        $bind = @ldap_bind($conn, $user, $pass);
        ldap_get_option($conn, LDAP_OPT_DIAGNOSTIC_MESSAGE, $extended_error);
        if (!empty($extended_error))
        {
            $errno = explode(',', $extended_error);
            $errno = $errno[2];
            $errno = explode(' ', $errno);
            $errno = $errno[2];
            $errno = intval($errno);
            if ($errno == 532)
                $err = 'Unable to login: Password expired';
        }
        elseif ($bind)
        {
            $base_dn = array("CN=Users,DC=". join(',DC=', explode('.', DOMAIN_FQDN)), 
                "OU=Users,OU=People,DC=". join(',DC=', explode('.', DOMAIN_FQDN)));
            $result = ldap_search(array($conn,$conn), $base_dn, "(cn=*)");
            if (!count($result))
                $err = 'Unable to login: '. ldap_error($conn);
            else
            {
                foreach ($result as $res)
                {
                    $info = ldap_get_entries($conn, $res);
                    for ($i = 0; $i < $info['count']; $i++)
                    {
                        if (isset($info[$i]['userprincipalname']) AND strtolower($info[$i]['userprincipalname'][0]) == strtolower($user))
                        {
                            session_start();
                            $username = explode('@', $user);
                            $_SESSION['foo'] = 'bar';
                            // set session variables...
                            break;
                        }
                    }
                }
            }
        }
    }
    // session OK, redirect to home page
    if (isset($_SESSION['foo']))
    {
        header('Location: /');
        exit();
    }
    elseif (!isset($err)) $err = 'Unable to login: '. ldap_error($conn);
    ldap_close($conn);
}
?>
<!DOCTYPE html><head><title>Login</title></head>
<style>
* { font-family: Calibri, Tahoma, Arial, sans-serif; }
.errmsg { color: red; }
#loginbox { font-size: 12px; }
</style>
<body>
<div align="center"><img id="imghdr" src="/img/logo.png" height="100" /><br><br><h2>Login</h2><br><br>
<div style="margin:10px 0;"></div>
<div title="Login" style="width:400px" id="loginbox">
    <div style="padding:10px 0 10px 60px">
    <form action="/login.php" id="login" method="post">
        <table><?php if (isset($err)) echo '<tr><td colspan="2" class="errmsg">'. $err .'</td></tr>'; ?>
            <tr>
                <td>Login:</td>
                <td><input type="text" name="username" style="border: 1px solid #ccc;" autocomplete="off"/></td>
            </tr>
            <tr>
                <td>Password:</td>
                <td><input type="password" name="password" style="border: 1px solid #ccc;" autocomplete="off"/></td>
            </tr>
        </table>
        <input class="button" type="submit" name="submit" value="Login" />
    </form>
    </div>
</div>
</div>
</body></html>
If you are looking only for authentication and nothing else, you may get away with only a few lines of code.
First, ensure you have ldap enabled in your php.
Here's pure php implementation:
(note that when doing it this way you should ensure that you DO HAVE a username and a password from a user - anonymous binding will almost always return true for AD)
$link = ldap_connect('domain.com'); // Your domain or domain server
if(! $link) {
    // Could not connect to server - handle error appropriately
}
ldap_set_option($link, LDAP_OPT_PROTOCOL_VERSION, 3); // Recommended for AD
// Now try to authenticate with credentials provided by user
if (! ldap_bind($link, 'username@domain.com', 'SomeSecret')) {
    // Invalid credentials! Handle error appropriately
}
// Bind was successful - continue
If you expect to do more fun stuff with Active Directory like pulling some information about currently logged in user I strongly recommend using a framework to do the heavy lifting for you. As already mentioned, adLDAP is a good one and if you run PHP 5.4 I dare recommending the AD-X library which I actively develop (you can install it via Composer).
With the AD-X library, you can verify a user's credentials using this code:
try {
    $link = new ADX\Core\Link('domain.com'); // Establish connection to AD
    $link->bind('username@domain.com', 'SomeSecret'); // Authenticate user
}
catch (ADX\Core\ServerUnreachableException $e) {
    // Unable to connect to server, handle error
}
catch (ADX\Core\InvalidCredentialsException $e) {
    // Invalid credentials supplied
}
catch (Exception $e) {
    // Something else happened, check the exception and handle appropriately
}
// Successfully authenticated if no exception has been thrown
Feel free to choose which suits you best. However, if you expect to do more than authenticate I strongly suggest you use a library for the ldap work - it will save you a lot of time and possibly frustration when things do not work as you would expect them to.
Also, if in doubt what information you can/should use to connect and to authenticate feel free to check my previous answer on this topic.