SELECT *
FROM employees e
WHERE NOT EXISTS
(
SELECT name
FROM eotm_dyn d
WHERE d.employeeID = e.id
)
I really think you should profile for such a question. Not only does it depend on the exact database product, but in theory it could also depend on the skew of your data.
However! By default I would say write the code that most clearly expresses your intent. You are after employee records without a matching eotm_dyn, so IMO the clearest code is WHERE NOT EXISTS. It probably won't matter, but I would use SELECT 1 (not SELECT name), since the name is not important in the "without a matching eotm_dyn logic.
Once you have code that expresses what you intend and works, then look at optimising based on profiling.
Assuming the column values involved can not be NULL -
LEFT JOIN/IS NULL is more efficient than NOT EXISTS - read this article for details.
They are equivalent.
NOT EXISTS is more efficient than LEFT JOIN/IS NULL - read this article for details.
Like Oracle, they are equivalent.
If you have trouble with the detail that the column values can not be null, yet use the LEFT JOIN / IS NULL - remember what a LEFT JOIN signifies. This link might help.