If you really want to use (less portable) scanf_s, from the C11 standard (n1570), Annex K 3.5.3.2 p.4:
The fscanf_s function is equivalent to fscanf except that the c, s, and [ conversion specifiers apply to a pair of arguments (unless assignment suppression is indicated by a *). The first of these arguments is the same as for fscanf. That argument is immediately followed in the argument list by the second argument, which has type rsize_t and gives the number of elements in the array pointed to by the first argument of the pair.
You need to give the lengths of your char * arguments:
scanf_s("%f %c %c", &inTemp, &inUnit, 1, &outUnit, 1);
Alternatively, just use scanf:
scanf("%f %c %c", &inTemp, &inUnit, &outUnit);
And, as always, check the return values.
In general, as scanf is somtimes useful for little quick-and-dirty programmes, it’s of less use for productive software, because handling errors is hard. Use fgets and sscanf/strtod/strtol/… instead.