NULL is a special value in SQL denoting the absence of data. As such, you cannot do queries like:
SELECT fields FROM table WHERE column = NULL
NULL cannot be compared to anything, including NULL itself. Instead, you'd need:
SELECT fields FROM table WHERE column IS NULL
However in your case you are really inserting an empty value in Sex and DOB.
And empty value is not NULL. You'd have to query for:
SELECT fields FROM table WHERE column = ''