The Standard says that std::tuple has the following member functions
constexpr tuple();
explicit tuple(const Types&...);
C
I guess the definition given in the standard is supposed to be pseudocode. That is the case with many of the definitions in the standard; it contains several requirements that are given verbally, but are satisfiable only with tricks like enable_if. This seems to be an example where the C++-like pseudocode notation can actually lead to illegal C++ when trying to instantiate such an empty tuple (or it might just be an omission).
Both stdlibc++ and libc++ have an explicit specialization for the zero-element tuple. For example, in stdlibc++:
  // Explicit specialization, zero-element tuple.
  template<>  
    class tuple<>
    {
    public:
      void swap(tuple&) noexcept { /* no-op */ }
    };
with an implicitly-defined unambiguous default constructor.
Libc++ does not explicitly declare the parameterless default constructor. Presumably the templated constructor is then chosen as default constructor for non-empty tuples.
Interestingly, the two libraries disagree on what members the empty tuple has. For example, the following compiles with libc++, but not with libstdc++:
#include <tuple>
#include <memory>
int main() {
  std::tuple<> t(std::allocator_arg, std::allocator<int>());
}
                                                                        I believe this is a minor error in the standard. Clearly, when the Types parameter pack is empty, the two constructor calls are equivalent and cannot be overloaded (see C++11 section 13). (Further note that the constructor using Types is not a member template either --if it was, then it would be a legal overload.).
In other words, this code will not compile:
template <typename... Types>
struct Test
{
  constexpr Test() {}
  explicit Test(Types const&...) { /* etc. */ }
};
int main()
{
  Test<> a;
  Test<int> b;
}
e.g., a g++ v4.8 snapshot outputs:
tt.cxx: In instantiation of ‘struct Test<>’:
tt.cxx:10:10:   required from here
tt.cxx:5:12: error: ‘Test<Types>::Test(const Types& ...) [with Types = {}]’ cannot be overloaded
   explicit Test(Types const&...) { /* etc. */ }
            ^
tt.cxx:4:13: error: with ‘constexpr Test<Types>::Test() [with Types = {}]’
   constexpr Test() {}
             ^
This can be fixed by using partial specialization:
template <typename... Types>
struct Test
{
  constexpr Test() {} // default construct all elements
  explicit Test(Types const&...) { /* etc. */ }
  // and all other member definitions
};
template <>
struct Test<>
{
  constexpr Test() {}
  // and any other member definitions that make sense with no types
};
int main()
{
  Test<> a;
  Test<int> b;
}
which will compile correctly.
It appears the standard wanted a constexpr default constructor was so that std::tuple<> var; could be written instead of writing std::tuple<> var(); or std::tuple<> var{}; because of the use of explicit with the other constructor. Unfortunately, its definition of std::tuple does not work for tuples of size zero. The standard does permit such in section 20.4.2.7 (relational operators) though, "For any two zero-length tuples, [...]". Oops! :-)
At first sight, the ambiguity would only matter at the point where it's called, and then you have normal overload resolution.