I have this simple class:
struct Worker
{
Worker() : done{false} {}
Worker(const Worker& rhs) : done{rhs.done}, qworker{} {}
Work
According to the C++11 standard std::function has an unconstrained constructor template that accepts any argument type:
template<class F> function(F f);
When you say qworker{std::move(rhs.qworker)} this first attempts to call a constructor taking std::initializer_list<std::function<void()>>. Because of the unconstrained constructor template shown above, a std::function<void()> can be constructed from any type, so you get an initializer_list with one member, like this:
{ std::function<void()>{std::move(rhs.qworker)} }
This is invalid, because rhs.qworker is not a callable object, but the error only happens when you try to invoke the function objects.
If you say qworker(std::move(rhs.qworker)) then the initializer list constructor is not a candidate and the move constructor is called instead.
There is a defect report against the standard (LWG 2132) which fixes this by preventing the function(F) constructor template being called unless the argument is a callable object. That prevents an initializer_list<function<void()>> being created, and instead qworker{std::move(rhs.qworker)} calls the move constructor, as intended. GCC 4.7 does not implement the resolution for LWG 2132, but GCC 4.8 does.