I am using PHPEXxcel to export an HTML Table generated using MYSQL and its like this.
Spreadsheets 101
There are many different spreadsheet file formats, each with their own different filename extensions, and that can be sent to a web browser using different mime types. These are described in the PHPExcel documentation, and each has its own different Writer in PHPExcel. You're mismatching two different formats
BIFF Format
Used by Microsoft Excel between versions 95 and 2003 File
extension: xls
PHPEXcel Writer: PHPExcel_Writer_Excel5
Mime Type: application/vnd.ms-excel
OfficeOpenXML Format
Used by Microsoft Excel since version 2007
File extension: xlsx
PHPEXcel Writer: PHPExcel_Writer_Excel2007
Mime Type: application/vnd.openxmlformats-officedocument.spreadsheetml.sheet
Don't mix and match: if you do, then Excel will (and justifiably) complain. If you want a BIFF file, use PHPExcel's BIFF Writer (Excel5), a file extension of .xls, and the mime type listed above for BIFF Format. If you want an OfficeOpenXML file, then use PHPExcel's Excel2007 Writer, a file extension of .xlsx, and the mime type listed above for OfficeOpenXML.
EDIT
Note that the examples provided with the PHPExcel distribution include 01simple-download-xls.php and 01simple-download-xlsx.php to demonstrate exactly what you want