When there is a { at the beginning of a statement, it will be interpreted as a block, which may contain zero or more statements. An block with no statements in it will have an empty continuation value.
In other words, in this case, {} is interpreted as an empty code block.
The statement ends after the ending brace }, which means that the next three characters +[] comprise a statement of their own.
At the beginning of an expression or statement, + is the unary plus operator, which coerces its operand to a number.
So +[] is the same as Number([]), which evaluates to 0.
In short, {} + [] is an empty code block followed by an array coerced to a number.
All that said, if you evaluate {} + [] inside an expression, it will return what you expect:
>> ({} + [])
"[object Object]"
Another interesting thing is that you cannot begin a statement with an object literal because the interpreter will try to parse it as a statement. Doing this
{ "object": "literal" };
will throw a syntax error.