You can use Visual C++ Express edition with MFC and the new library (from BCGSoft) to create office like GUI. It's powerful and there is a lot of documentation and support on community sites:
- http://www.codeproject.com
- http://www.codeguru.com.
If you are new in programming, I think you start directly with C# and .net, WinForms offer more tools and its simple to start. and with the mono you can deploy on other platforms as mac OS or LINUX.
To start download the Visual C# Express Edition, it's free.