I have two files. One of them defines a set of number-value pairs as follows (fileA):
1 asm
2 assert
3 bio
4 bootasm
5 bootmain
6
This might work for you (GNU sed):
sed 's|^\s*\(\S*\)\s*\(.*\)$|/^\2\\>/s//\1/|' fileA | sed -f - fileB
awk 'NR==FNR{a[$2]=$1;next}{$1=a[$1];}1' fileA fileB
NR==FNR{a[$2]=$1;next} => This is true when the fileA is processed. An associative array is formed where the index is the 2nd column with the 1st column as its value.
{$1=a[$1];} => When the second file is processed, Replace the 1st column with the appropriate value stored in the array.
1 => Print every line.