There's no cross-browser way of doing it.
The best you can achieve is nested ordered lists:
<ol>
<li>Item 1
<ol>
<li>Subitem 1</li>
</ol>
</li>
</ol>
and then style each nested list to have a different type:
ol {
list-style-type: upper-roman;
}
ol ol {
list-style-type: decimal;
}
Hope this helps!