const is a proposed feature of ECMAScript Harmony (together with a properly block-scoped let it is supposed to replace var and implicit globals). ECMAScript Harmony is a grab-bag of ideas for the next versions of ECMAScript.
const was also a part of ECMAScript 4.
ECMAScript 4 was never released and never will be, and ECMAScript Harmony will only be released in a couple of years. Therefore, you cannot reliably use it.
There are some implementations or derivatives of ECMAScript that implement const (ActionScript, for example). There are also some implementations that accept const as a synonym for var (IOW, you can use const, but it won't give you any protection.)
However, unless you absolutely can guarantee that your code will only run on very specific versions of very specific implementations of very specific derivatives of ECMAScript, it's probably better to avoid it. (Which is a real shame, because const and especially let are a huge improvement over var and implicit globals.)