The traditional way to write the argv argument is char *argv[] which gives more information about what it is, an array of pointers to characters (i.e. an array of strings).
However, when passing an array to a function it decays to a pointer, leaving you with a pointer to pointer to char, or char **.
Of course, double asterisks can also be used when dereferencing a pointer to a pointer, so without the added context at the end of the question there are two answers to the question what ** means in C, depending on context.
To continue with the argv example, one way to get the first character of the first element in argv would be to do argv[0][0], or you could use the dereference operator twice, as in **argv.
Array indexing and dereferencing is interchangeable in most places, because for any pointer or array p and index i the expression p[i] is equivalent to *(p + i). And if i is 0 then we have *(p + 0) which can be shortened to *(p) which is the same as *p.
As a curiosity, because p[i] is equivalent to *(p + i) and the commutative property of addition, the expression *(p + i) is equal to *(i + p) which leads to p[i] being equal to i[p].
Finally a warning about excessive use of pointers, you might sometime hear the phrase three-star programmer, which is when one uses three asterisks like in *** (like in a pointer to a pointer to a pointer). But to quote from the link
Just to be clear: Being called a ThreeStarProgrammer is usually not a compliment
And another warning: An array of arrays is not the same as a pointer to a pointer (Link to an old answer of mine, which also shows the memory layout of a pointer to a pointer as a substitute of an array of arrays.)
