Jazz Scheme is an open source scheme environment built on Gambit Scheme and it seems to aggressively promote industrial uses, check it out:
Jazz Scheme
They report new uses in their news:
Jazz Scheme News
According to this page, Scheme is (or was) in use at: DEC, TI, Tektronix, HP, and Sun.
This guy's LinkedIn CV reports using Chez Scheme at Disney.
Just googling around a little can reveal a lot. In this case, it bears out the observation that I once heard that Scheme use is pretty ubiquitous, just not very public.