You can't assign to arrays (as the error message states). Copy the strings instead:
snprintf(aStruct->member, sizeof(aStruct->member), "%s", someString);
Or, if you want to shoot yourself in the foot (prone to buffer overruns):
strcpy(aStruct->member, "the string");
Or, if you want to shoot yourself in the foot and not notice it (safe of buffer overruns, but doesn't NUL-terminate the string if too long):
strncpy(aStruct->member, "the string", sizeof(aStruct->member));