Lately I\'ve been using # instead of // for doing single line comments inside my Code. However, I see must of the people prefer //.
You can use #, but // is much more common.
It is also the agreed upon Code Convention in PEAR.
I would only suggest you use // or /* */. As your programs grow you may wish to use a documentator like phpdoc to automate documentation for your program and most of these documentators as well as IDE's will only accept these two.