FROM wcm:
If you don't want to use VBA, you can use this
replace colnr with the number you want
=MID(ADDRESS(1,colnr),2,LEN(ADDRESS(1,colnr))-3)
Please be aware of the fact that this formula is volatile because of the usage of the ADDRESS function. Volatile functions are functions that are recalculated by excel after EVERY change.
Normally excel recalculates formula's only when their dependent references changes.
It could be a performance killer, to use this formula.