The only site I've done with Ruby at work is using Rails, but I'd like to try Merb.
Other than that I do a lot of little utility programs in Ruby - for instance an app that reads RSS feeds and imports new posts into a dabase.
It's fun, so I also write some dumb stuff just because it's so quick. Yesterday I wrote an app to play the Monty Hall problem 100,000 times to help a friend convince her professor that switching is the correct strategy.