Before data.table v1.9.8, the default behavior of unique.data.table method was to use the keys in order to determine the columns by which the unique combinations should be returned. If the key was NULL (the default), one would get the original data set back (as in OPs situation).
As of data.table 1.9.8+, unique.data.table method uses all columns by default which is consistent with the unique.data.frame in base R. To have it use the key columns, explicitly pass by = key(DT) into unique (replacing DT in the call to key with the name of the data.table).
Hence, old behavior would be something like
library(data.table) v1.9.7-
set.seed(123)
a <- as.data.frame(matrix(sample(2, 120, replace = TRUE), ncol = 3))
b <- data.table(a, key = names(a))
## key(b)
## [1] "V1" "V2" "V3"
dim(unique(b))
## [1] 8 3
While for data.table v1.9.8+, just
b <- data.table(a)
dim(unique(b))
## [1] 8 3
## or dim(unique(b, by = key(b)) # in case you have keys you want to use them
Or without a copy
setDT(a)
dim(unique(a))
## [1] 8 3