std::string provides const char* c_str ( ) const which:
Get C string equivalent
Generates a null-terminated sequence of cha
I addition to the rationale provided in the specification (unexpected surprises), if you're mixing C API calls with std::string, you really need to get into the habit of using the ::c_str() method. If you ever call a varargs function (eg: printf, or equivalent) which requires a const char*, and you pass a std::string directly (without calling the extraction method), you won't get a compile error (no type checking for varargs functions), but you will get a runtime error (class layout is not binary identical to a const char*).
Incidentally, CString (in MFC) takes the opposite approach: it has an implicit cast, and the class layout is binary-compatible with const char* (or const w_char*, if compiling for wide character strings, ie: "Unicode").