This is probably best explained with an example. I have the following table, where the \"A\" cell spans two rows, and the \"B\" cell spans two columns.
\\begin{t
\multirow{2}{*}{\hfil A}
\hfil will automatically calculate the width of the cell and insert a half-width space
To insert a full cell-width space, which will right-justify a single cell, use \hfill.
There are also \vfil and \vfill analogues.
I think you need to do that with a fake \multicolumn:
\multicolumn{1}{c}{\multirow{2}{*}{A}} & \multicolumn{2}{c}B} \\
Inspiration from this FAQ.
I came across a similar problem, but had to use \multirow{specified width}{} instead of \multirow{*}{}. Nesting multirow inside a multicolumn does not work in this case.
I found \multirow{specified width}{\centering text} to work instead.
That is could be helpful for someone
\begin{tabular}{|c c | c|c|c|}
\hline
\multicolumn{2}{|c}{\multirow{2}{*}{Modulation}} & \multicolumn{3}{|c|}{M} \\
\cline{3-5}
& & 2 & 4 & 8 \\
\hline
\multirow{3}*{\hfil SNR=$\begin{cases} \\ \\ \end{cases}$} & STMA & xx dB & xx dB & xx dB\\
& QTMA & xx dB & xx dB & xx dB \\
& POSTMA & xx dB & xx dB & xx dB\\
\hline
\end{tabular}