I know the big-O complexity of this algorithm is O(n^2), but I cannot understand why.
int sum = 0;
int i = 1; j = n * n;
while (i++ < j--)
s
big-O complexity ignores coefficients. For example: O(n), O(2n), and O(1000n) are all the same O(n) running time. Likewise, O(n^2) and O(0.5n^2) are both O(n^2) running time.
In your situation, you're essentially incrementing your loop counter by 2 each time through your loop (since j-- has the same effect as i++). So your running time is O(0.5n^2), but that's the same as O(n^2) when you remove the coefficient.