I have a DataFrame which contains a lot of intraday data, the DataFrame has several days of data, dates are not continuous.
2012-10-08 07:12:22 0.0
Just to give an alternative answer to @DSM, look at this other answer from @Psidom
It would be something like:
pd.to_datetime(df['DateTime']).dt.date.unique()
It seems to me that it performs slightly better