I\'ve install different provisioning profile in my xcode 5, before for remove it you had a session with all provisioning profile installed on the mac, but now this session disap
You can delete the files directly from ~/Library/MobileDevice/Provisioning Profiles
~/Library/MobileDevice/Provisioning Profiles
Open finder, ⌘-Shift-G, and paste in the above path. Restart Xcode afterward.
Check out this related question for other suggestions.