I have a field with multiple options and I want to allow it to have only one option selected at the same time but user can hold CTRL key and
Why don't you want to remove the multiple attribute? The entire purpose of that attribute is to specify to the browser that multiple values may be selected from the given select element. If only a single value should be selected, remove the attribute and the browser will know to allow only a single selection.
Use the tools you have, that's what they're for.