I am writing a Bash shell script for Mac that sends an email notification by opening an automator application that sends email out with the default mail account in Mail.app. The
1) Why not configure postfix to handle outbound mail only and relay it via a mail gateway? Its biggest advantage is that it is already installed on OS X clients.
2) Install and configure one of the lightweight MTAs that handle only outbound mail, like nullmailer or ssmtp (available via MacPorts).
In both cases use mailx(1) (or mutt if you want to get fancy) to send the mails from a shell script.
There are several questions on Server Fault that go into the details.