Prolog is a logic programming language, whereas Haskell is a functional language. Functional languages are based on the concept of a function which takes a number of arguments and computes a value.
Prolog, on the other hand, does not have functions. Instead, predicates are used to prove a "theorem". Prolog predicates do not compute a value, they can answer "yes" or "no" and optionally bind input variables to values:
The usefulness of functional and logic programming often overlap. Functional programming has gained quite a bit of traction lately, while Prolog is still much a niche language, much due to the fact that it is much more different from the common concepts of functions and methods of mainstream OOP than functional programming is, and often considered (very) difficult to learn.
Certain problems become almost trivial to implement in Prolog, especially in combination with constraint solvers.
You can read more about logic programming on Wikipedia.