It's worthwhile to learn lots of different languages, from lots of different paradigms. Learning Java, C++, C#, and Python doesn't count, since they are all instances of the same paradigm.
As assembly is at the root (well, close to the root) of all languages, I for one say that it is worthwhile to learn assembly.
Then again, it's worthwhile to learn a functional programming language, logic programming, scripting languages, math-based languages. You only have so much time, so you do have to pick and choose.
