Paul Graham posted an article several years ago about why Python programmers made better Java programmers. (http://www.paulgraham.com/pypar.html)
Basically, regardless of whether the new language is relevant to the company's current methodology, learning a new language means learning new ideas. Someone who is willing to learn a language that isn't considered "business class" means that he is interested in programming, beyond just earning a paycheck.
To quote Paul's site:
And people don't learn Python because
it will get them a job; they learn it
because they genuinely like to program
and aren't satisfied with the
languages they already know.
Which makes them exactly the kind of
programmers companies should want to
hire. Hence what, for lack of a better
name, I'll call the Python paradox: if
a company chooses to write its
software in a comparatively esoteric
language, they'll be able to hire
better programmers, because they'll
attract only those who cared enough to
learn it. And for programmers the
paradox is even more pronounced: the
language to learn, if you want to get
a good job, is a language that people
don't learn merely to get a job.
If an employer was willing to pay for the cost of learning a new language, chances are the people who volunteered to learn (assuming it wasn't a mandatory class) would be the same people to are already on the "fast track".
