phpinfo
_ENV[\"ORACLE_HOME\"] C:\\oracle\\instantclient_11_2\\ _ENV[\"OS\"] Windows_NT _ENV[\"Path\"] C:\\WINDOWS\\system32;C:\\WINDOWS;C:\\WINDOWS\\System32
https://forums.oracle.com/forums/message.jspa?messageID=1742926#1745145
There are several potential solutions on that page ranging from re-installing xampp to checking permissions to using native php oci_connect(). Have you tried any of these things?
oci_connect()