Is it possible to have an black outline on my 3d models with three.js?
I would have graphics which looks like Borderlands 2. (toon shading + black outlines)
Yes it is possible but not in a simple out-of-the-box way. For toon shading there are even shaders included in /examples/js/ShaderToon.js
For the outlines I think the most commonly suggested method is to render in two passes. First pass renders the models in black, and slightly larger scale. Second pass is normal scale and with the toon shaders. This way you'll see the larger black models as an outline. It's not perfect but I don't think there's an easy way out. You might have more success searching for "three.js hidden line rendering", as, while different look, somewhat similar method is used to achieve that.