Recently I have updated from MySQL 5.1 to 5.5 and after few weeks the following error message was displayed each time I access the phpMyAdmin application:
Run sudo mysql_upgrade -u root -p --force
sudo mysql_upgrade -u root -p --force
Then restart mysql
i.e. sudo service mysql restart or sudo service mysqld restart depending on the version and distribution you have
sudo service mysql restart
sudo service mysqld restart
You need to logout of phpMyAdmin then login for the change to take effect.