There is a general trick often used in programming - paying with memory for operation speedup. If you have lots of employees, and you are going to query a significant portion of them, one by one (say, 75% will be queried at one time or the other), then query everything, cache it (very important!), and complete the lookup in memory. The next time you query, skip the trip to RDBMS, go straight to the cache, and do a fast look-up: a roundtrip to a database is very expensive, compared to an in-memory hash lookup.
On the other hand, if you are accessing a small portion of employees, you should query just one employee: data transfer from the RDBMS to your program takes a lot of time, a lot of network bandwidth, a lot of memory on your side, and a lot of memory on the RDBMS side. Querying lots of rows to throw away all but one never makes sense.