I have a long list selector
When the SelectionChanged event occurs, the senderparameter of the event handler represents the object that triggered this event. It is of type Object, but you can cast it to match your specific control type.
In this case, the LongListSelector :
var myItem = ((LongListSelector) sender).SelectedItem as Model;
(Model represents the type of data your control handles).
Afterwards, look for that item in the ItemsSource and retrieve its value :
var myIndex = ((LongListSelector) sender).ItemsSource.IndexOf(myItem);
You have named your control, so instead of (sender as LongListSelector), you could use its name, BTDevices, but the code lines I wrote was intended to show you what's what with the sender object.
Alternatively (and this is a more elegant way), shown by bland, you could use the EventArgs for selection : e.AddedItems[0]