I am trying to draw a bounding box around the white blob in the image below:
As the 20,000th viewer of this question, I'll answer what I think the asker is actually asking.
To render a rectangle on the page, you just need to properly interpret the bounding box for the shape. You've already computed this in s(idx).BoundingBox
Thus, add these two lines to your script:
bb = s(idx).BoundingBox;
rectangle('Position',[bb(1) bb(2) bb(3) bb(4)],'EdgeColor','green');
and you'll get: