a = [('when', 3), ('why', 4), ('throw', 9), ('send', 15), ('you', 1)]
b = ['the', 'when', 'send', 'we', 'us']
c=[] # a list to store the required tuples
#compare the first element of each tuple in with an element in b
for i in a:
if i[0] not in b:
c.append(i)
print(c)