First off there seems to be no way to get an exact match using a full-text search. This seems to be a highly discussed issue when using the full-text search method and there
This will give you the movies that contain the exact phrase "Toy Story", ordered by their popularity.
SELECT
m.[ID],
m.[Popularity],
k.[Rank]
FROM [dbo].[Movies] m
INNER JOIN CONTAINSTABLE([dbo].[Movies], [Title], N'"Toy Story"') as [k]
ON m.[ID] = k.[Key]
ORDER BY m.[Popularity]
Note the above would also give you "The Goonies Return" if you searched "The Goonies".