@echo off
setlocal EnableDelayedExpansion
set "string=C:\Users\testing\AppData\Local\Test\abc123\643456\VSALBT81_COM"
for /L %%d in (0,1,9) do set "string=!string:\%%d=\ %%d!"
for /F "tokens=2" %%a in ("%string%") do for /F "delims=\" %%b in ("%%a") do echo Number: [%%b]