import numpy as np
n = np.reshape([], (0, 2))
for x in [[2,3],[4,5],[7,6]]:
n = np.append(n, [x], axis=0)
Instead of np.append you can also use n = np.vstack([n,x]). I also agree with @Bi Rico that I also would use a list, if n does not need to accessed within the loop.