With the standard Rails form_for, I was able to pass ajax requests though select and collection_select helpers as such:
<%= address.collection_select :cou
It seems the valid way to do this now is:
:remote => true, :html => { :data => { :url => '/yoururl', :type => :json } }
which may look a little better with ruby 1.9 hash syntax as:
remote: true, html: { data: { url: '/yoururl', type: :json } }
https://github.com/plataformatec/simple_form/wiki/HTML5-Attributes