Given the following XAML code that with a ListControl like behavior:
According to MSDN Magazine article "Charting with DataTemplates":
[...]the DataTemplate would need access to the index of the particular data item in the collection. But it's easy enough to include this information in the business object[...]
So, unless there was a change in .NET 4, there is no "index of this item" property unless it is explicitly included in the model.