Given the following table
123456.451 entered-auto_attendant
123456.451 duration:76 real:76
139651.526 entered-auto_attendant
139651.526 duration:62 real:
you didn't give an expected output, does this work for you?
awk '!a[$1]++' file
with your data, the output is:
123456.451 entered-auto_attendant
139651.526 entered-auto_attendant
139382.537 entered-auto_attendant
and this line prints only unique column1 line:
awk '{a[$1]++;b[$1]=$0}END{for(x in a)if(a[x]==1)print b[x]}' file
output:
139382.537 entered-auto_attendant