I have a few websites for work that live outside of the corporate LAN -- and, therefore, out of direct-communication range of Active Directory (A/D) -- but for which I would
You might want to take a look @ these two resources. The first will provide you with everything you want to know about active directory, and the second will show you how to connect.
You might have challenges connecting to the remote AD server though. So as a potential work around, I would consider having the web application call an authentication webservice that resides on the corporate network.