Is there a definitive method of creating either a PDF or a MS Word Doc file within the app and email it immediately (and possibly, also store it).
I have been trying
I'm working right now with JasperReports, an open source library to create reports in Java and export them to PDF, DOC, XLS... Using it in conjunction with iReport to create a group of templates makes it really easy to create files filled with content from different types of sources (I'm using JavaBeans).
If you don't like the idea of having static templates (That's a bit annoying depending on your needs), you can always take a look at DynamicJasper (The examples on the website are great).
Good Luck!