There are some podcasts about the feature itself and how it can be used:
- Inside C# 4.0: dynamic typing, optional parameters, covariance and contravariance
- C# 4.0 New Features - COM Interop Enhancements
- deCast - Dynamic Xml with C# 4.0 "will illustrate how you can take advantage of the dynamic functionality enabled in C# 4.0 to access Xml data in a more natural way"