Interpolated strings is one of the new features of C# 6.0.
According to MSDN, the syntax of the embedded C# expressions can contain an optional, comma-separated val
The number is the alignment, documented in the Alignment Component here.
The formatted data in the field is right-aligned if alignment is positive and left-aligned if alignment is negative.
In your example, alignment will pad the p.ProcessName
with spaces if it is less than 5
characters long. Where string length is less than the absolute value of alignment (like in your example), alignment has no effect.
Example
var text = "MyText";
Console.WriteLine($"x{text}x");
Console.WriteLine($"x{text, 3}x");
Console.WriteLine($"x{text, 10}x");
Console.WriteLine($"x{text, -10}x");
Result
xMyTextx
xMyTextx
x MyTextx
xMyText x