I\'ve dealt with instances where I would throw/rethrow an exception knowing that the code surrounding it would catch the specific exception. But is there any time you would
Here's the thing ... it is about "layers", or "encapsulation", or "low coupling". At some place in your codebase, you're writing a method to do something. Say it's a public method. Therefore, it should not assume much or anything about the caller ... rather, it should merely do the job it is supposed to do, regardless of who is calling it and what context the caller is in.
And if, for some reason, it cannot complete its job, then it needs to tell the caller "Sorry, I couldn't do that, and here's why". Exceptions are an excellent mechanism to let it tell the caller that (not the only mechanism, but the best mechanism I've ever seen for most cases).
So, when you throw the exception, you have no idea whether it will be caught or not ... because you're exposing a public method and you have no idea who might choose to call it and why.
The catching of the exception is the job of the "context". For example, say you're writing a library with public methods that might throw exceptions. Then, say you're using that library from a Windows Forms app. The Windows Forms app might catch exceptions and show a message box to the user.
But later, you might use the same library from a Windows Service. The Service would be more likely to catch the exception, log it, return an error to the original caller, but keep running so it can process further requests.
So the exception is like a contractual agreement between the caller and the provider. The provider says, "I'll either do the job or tell you why I can't. What you do from there is your own business." And the caller says, "OK, if you can't do the job, just tell me why, and I'll decide what to do in that case."